Nucleophilic Addition to 2-Imidazolines. A Ketone Synthesis via Tetrahydrofolate Coenzyme Models

DOI: 10.1039/c39820000282

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 282 - 283 (1982)

Update date:2022-08-04

Topics:

Authors:

Anderson, Michael W.

Jones, Raymond C. F.

Saunders, John

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39820000282

2-Alkyl-1-benzyl-3-methyl-2-imidazolinium salts with Grignard reagents give addition products that are hydrolysed to ketones; 2-imidazolines and 2-imidazolinium salts with hydride reagents afford N-alkylated 1,2-diaminoethanes.

Full text of DOI:10.1039/c39820000282

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:3-Benzyl-1-methyl-2-(1-methyl-nonyl)-4,5-dihydro-3H-imidazol-1-ium; iodide

Cas No:82461-97-0

R&D Labs maybe for 82461-97-0

Ningbo J&S Botanics Inc.

Contact:86-574-26865651

Address:529 YuanBaoShan Road, Beilun District
Synochem Ingredients Corp., Ltd.

Contact:+86-512-5636 2180

Address:Zhangjiagang Free Trade Zone
Jiangyin Tenghua Import&Export Co.,Ltd.

Contact:+86-510-86263875

Address:Room 402-B,9 Yanling Road, Jiangyin,Jiangsu, China
Haitong Chemical Industrial Co.,Ltd.

website:https://www.haitonglongwin.com/

Contact:+86-022-66221018

Address:18-701, No.99, The 4th Street, TEDA,
Huayi Isotopes Co.

Contact:+ 86 512 52491118

Address:1 Fuyu Road, Haiyu TownChangshu, Jiangsu, China

Relevant to this article

Synthesis and study of a spin-labeled cyclophosphamide analogue, 3-(1-oxy-2,2,6,6-tetramethyl-4-piperidinyl)cyclophosphamide

Doi:10.1021/jm00351a021
(1982)
Synthesis, protease inhibition, and antileishmanial activity of new benzoxazoles derived from acetophenone or benzophenone and synthetic precursors

Doi:10.1007/s00044-017-1824-y
(2017)
Unsymmetrical pnp-pincer type phosphaalkene ligands protected by a fused-ring bulky eind group: Synthesis and applications to rh(i) and ir(i) complexes

Doi:10.1021/acs.organomet.6b00113
(2016)
UDP-N-trifluoroacetylglucosamine as an alternative substrate in N- acetylglucosaminyltransferase reactions

Doi:10.1016/S0008-6215(97)10033-7
(1998)
A diastereoselective synthesis of 2,4-disubstituted piperidines: scaffolds for drug discovery.

Doi:10.1021/ol006589o
(2000)
Ligand effects in the metal catalysed reactions of N-aryldiazoamides: Ylide formation vs. insertion reactions

Doi:10.1016/S0040-4020(98)00525-0
(1998)

Article Doi