CYCLOPROPANE FORMATION FROM 4,5-UNSATURATED THIOPHENYLETHERS. CONVERSION OF LIMONENE INTO CAR-2-ENE

DOI: 10.1016/0040-4020(82)80212-3

Source and publish data:

Tetrahedron p. 693 - 696 (1982)

Update date:2022-08-02

Topics:

Authors:

Fourneron, J. D.

Harwood, L. M.

Julia, M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4020(82)80212-3

Strong bases can abstract a proton α to a double bond.A phenylthio group γ to that double bond can be eliminated at the same time leading to a cyclopropane ring.The procedure is illustrated by a conversion of limonene into car-2-ene.

Full text of DOI:10.1016/0040-4020(82)80212-3

Products guided by the article

Product name:Toluene-4-sulfonic acid 5-methyl-2-(1-methyl-1-phenylsulfanyl-ethyl)-hex-4-enyl ester

Cas No:82470-82-4

R&D Labs maybe for 82470-82-4

Nantong LiKai Chemical Co.,Ltd

Contact:+86-513-89068669

Address:Jincheng Science Park
shanghai payne pharm co.,ltd.

Contact:+86-021-58123769

Address:No.780 of Cailun Road,Zhangjiang Hi-tech Park,Pudong,Shanghai
Shanghai Apeptide Co., Ltd.

website:http://www.apeptides.com/en/

Contact:+86-21-60871011

Address:No. 80 Chuanshan Shuyuan Steet,Pudong,Shanghai
Wuhan Fortuna Chemical Co.,Ltd

website:http://www.fortunachem.com

Contact:86-27-59207850

Address:Add: Room 2015, No.2 Building, Kaixin Mansion No.107 Jinqiao Avenue, Wuhan, China
Weinan Rigel Pharm Co., Ltd.

Contact:+86-913-2223392

Address:No. 32, Xinanjing Road, Weinan City, Shaanxi Province, 714000, China

Relevant to this article

Preparation, Stereochemistry, and Nuclear Magnetic Resonance Spectroscopy of 4-Hydroxy(acetoxy)bicyclo<5.1.0>octanes. Synthesis of (-)- and (+/-)-8,8-Dimethylbicyclo<5.1.0>oct-2-en-4-one

Doi:10.1021/jo00141a029
(1982)
Inter- and intramolecular reductive coupling reactions: an approach to the phorbol skeleton.

Doi:10.1021/ol006301v
(2000)
Oligomethylene-Bridged Dinuclear Triorganotin Triflates and Diphenylphosphinates. Ion Pairing in the Solid State and Electrolytic Dissociation in Solution of [Ph₂Sn(CH₂) _nSnPh₂X](O₃SCF₃) (X

Doi:10.1021/om049773c
(2004)
Molecular recognition between adenine or 2,6-diaminopurine and copper(II) chelates with N,O₂,S-tripodal tetradentate chelators having thioether or disulfide donor groups

Doi:10.1016/j.jinorgbio.2015.05.014
(2015)
Saponin and Sapogenol. XXXIII. Chemical constituents of the seeds of Vigna angularis (Willd.) Ohwi et Ohashi (3) Azukisaponins V and VI

Doi:10.1248/cpb.31.683
(1983)
α-Nitro Ketones and Esters from Acylimidazoles

Doi:10.1021/jo00142a008
(1982)

Article Doi