SYNTHESE UND EIGENSCHAFTEN STABILER HEXAMETHYLBENZOL(PHOSPHIN)DIMETHYL- UND -DIHYDRIDO-RUTHENIUM(II)-KOMPLEXE

DOI: 10.1016/S0022-328X(00)84330-2

Source and publish data:

Journal of Organometallic Chemistry p. 289 - 300 (1982)

Update date:2022-08-05

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Authors:

Werner, H.

Kletzin, H.

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Article abstract of DOI:10.1016/S0022-328X(00)84330-2

The dimethylruthenium(II) compounds C6Me6(PR3)Ru(CH3)2 (IV-VI, R3=Me3, MePh2, Ph3) have been prepared from C6Me6(PR3)RuCl2 (I-III) and LiCH3.They react with CF3COOH under stepwise elimination of CH4 to give C6Me6(PR3)RuCH3(OCOCF3) (VII-IX) and C6Me6(PR3)R

Full text of DOI:10.1016/S0022-328X(00)84330-2

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