STEREOSELECTIVE SYNTHESIS OF 1-O-ACYL-D-GLUCOPYRANOSE FROM 1-HYDROXY SUGAR AND ACYL FLUORIDES BY THE PROMOTION OF CESIUM FLUORIDE

Article abstract of DOI:10.1246/cl.1982.861

In the presence of cesium fluoride, the reaction of 2,3,4,6-tetra-O-benzyl-D-glucopyranose with acyl fluorides affords the corresponding glucosyl esters in good yields under essentially neutral condition.The α/β ratio of produced glucosyl esters is greatl