STEREOSELECTIVE SYNTHESIS OF 1-O-ACYL-D-GLUCOPYRANOSE FROM 1-HYDROXY SUGAR AND ACYL FLUORIDES BY THE PROMOTION OF CESIUM FLUORIDE

DOI: 10.1246/cl.1982.861

Source and publish data:

Chemistry Letters p. 861 - 862 (1982)

Update date:2022-09-26

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Authors:

Shoda, Shin-ichiro

Mukaiyama, Teruaki

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Article abstract of DOI:10.1246/cl.1982.861

In the presence of cesium fluoride, the reaction of 2,3,4,6-tetra-O-benzyl-D-glucopyranose with acyl fluorides affords the corresponding glucosyl esters in good yields under essentially neutral condition.The α/β ratio of produced glucosyl esters is greatl

Full text of DOI:10.1246/cl.1982.861

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