Tetrahedron Letters p. 6879 - 6882 (1989)
Update date:2022-08-05
Topics:
Suzuki, Keisuke
Maeta, Hideki
Suzuki, Toshiyuki
Matsumoto, Takashi
Combination of Cp2ZrCl2-AgBF4 (molar ratio= 0.5:1) is highly effective in promoting rapid and high-yield glycosidation of tetra-O-benzyl-D-mannopyranosyl fluoride.Yields are excellent in all cases examined and high α-selectivity is achievable by the reaction in benzene at room temperature.
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