Journal of Organic Chemistry p. 4246 - 4249 (1982)
Update date:2022-08-05
Topics:
Crumrine, David S.
Brodbeck, Charles M.
Dombrowski, Paul H.
Haberkamp, Thomas J.
Kekstas, Rita J.
et al.
N-Nitrosodiphenylamine, N-nitroso(2-nitrophenyl)phenylamine, N-nitroso(3-methylphenyl)phenylamine, and N-nitrosocarbazole were irradiated in degassed neutral solution to give the corresponding diarylamine as the initial photoproduct.The effects of changing solvents, concentrations, and substituents and of adding catalysts were examined.Quantum yield studies, sensitization work, and ESR studies were used to study the mechanism of this photolysis.
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