Inert Carbon Free Radicals. 3. Monofunctionalized Radicals from Perchlorotriphenylcarbenium Hexachloroantimonate

DOI: 10.1021/jo00144a019

Source and publish data:

Journal of Organic Chemistry p. 4498 - 4505 (1982)

Update date:2022-08-04

Topics: Homolytic Cleavage Counterion redox reaction Resonance stabilization Radical scavenger Hyperconjugation

Authors:

Ballester, Manuel

Riera, Juan

Castaner, Juan

Rodriguez, Antonio

Rovira, Concepcion

Veciana, Jaime

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Article abstract of DOI:10.1021/jo00144a019

Perchlorotriphenylcarbenium hexachloroantimonate (2) is prepared from perchlorotriphenylmethyl radical (PTM; 1) and SbCl5.Salt 2 by hydrolisis or ammonolysis yields perchlorofuchsone (3) or NH-tetradecachlorofuchsonimine (4), respectively, two quinonoid c

Full text of DOI:10.1021/jo00144a019

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