AUTOXIDATIVE RINGVERENGUNG VON 1,2-BIS(TRIMETHYLSILOXY)-CYCLOBUTENEN

DOI: 10.1016/S0040-4039(00)87964-2

Source and publish data:

Tetrahedron Letters p. 2635 - 2638 (1983)

Update date:2022-09-26

Topics:

Authors:

Heine, Hans-Georg

Hartmann, Willy

Knops, Hans-Joachim

Priesnitz, Uwe

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Article abstract of DOI:10.1016/S0040-4039(00)87964-2

1,2-Bis(trimethylsiloxy)cyclobutenes undergo facile autoxidative ring contraction yielding 1-trimethylsiloxycyclopropane carboxylic acid trimethylsilyl esters as major products.The results are discussed in terms of a mechanism involving electron transfer and intermediate formation of dioxiranes.

Full text of DOI:10.1016/S0040-4039(00)87964-2

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