Selective functional transformation of 1,2-diols via organophosphorus reagents

Article abstract of DOI:10.1080/10426509908546318

A new synthesis of 1,3,2λ⁵-dioxaphospholanes was realized by direct reaction of dibromotriphenylphosphorane with 1,2-diols. Ring opening studies were performed with or without electrophilic activation (Lewis acids or hydrogen bonding) in order to substitute selectively one of the hydroxy function.

Full text of DOI:10.1080/10426509908546318

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Phosphorus, Sulfur, and
Silicon and the Related
Elements
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Selective Functional
Transformation
of 1,2-Diols Via
Organophosphorus
Reagents
Jean-Luc Pirat , Michel Carteron , Annie-
Francoise Maggio , Stephanie Bot &
Henri-Jean Cristau
a Laboratoire de Chimie Organique,
ESA 5076 du C.N.R.S. Ecole Nationale
Supérieure de Chimie de Montpellier
8 rue de l'Ecole Normale, 34296
Montpellier Cedex 5, FRANCE Fax:
b Laboratoire de Chimie Organique,
ESA 5076 du C.N.R.S. Ecole Nationale
Supérieure de Chimie de Montpellier
8 rue de l'Ecole Normale, 34296
Montpellier Cedex 5, FRANCE Fax:
c Laboratoire de Chimie Organique,
ESA 5076 du C.N.R.S. Ecole Nationale
Supérieure de Chimie de Montpellier
8 rue de l'Ecole Normale, 34296
Montpellier Cedex 5, FRANCE Fax:

d Laboratoire de Chimie Organique,
ESA 5076 du C.N.R.S. Ecole Nationale
Supérieure de Chimie de Montpellier
8 rue de l'Ecole Normale, 34296
Montpellier Cedex 5, FRANCE Fax:
e Laboratoire de Chimie Organique,
ESA 5076 du C.N.R.S. Ecole Nationale
Supérieure de Chimie de Montpellier
8 rue de l'Ecole Normale, 34296
Montpellier Cedex 5, FRANCE Fax:
Published online: 17 Mar 2008.
To cite this article: Jean-Luc Pirat , Michel Carteron , Annie-Francoise
Maggio , Stephanie Bot & Henri-Jean Cristau (1999) Selective Functional
Transformation of 1,2-Diols Via Organophosphorus Reagents, Phosphorus,
Sulfur, and Silicon and the Related Elements, 144:1, 609-612, DOI:
10.1080/10426509908546318
To link to this article: http://dx.doi.org/10.1080/10426509908546318
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