Selective functional transformation of 1,2-diols via organophosphorus reagents

DOI: 10.1080/10426509908546318

Source and publish data:

Phosphorus, Sulfur and Silicon and the Related Elements p. 609 - 612 (1999)

Update date:2022-08-03

Topics:

Authors:

Pirat, Jean-Luc

Carteron, Michel

Maggio, Annie-Francoise

Bot, Stephanie

Cristau, Henri-Jean

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Article abstract of DOI:10.1080/10426509908546318

A new synthesis of 1,3,2λ⁵-dioxaphospholanes was realized by direct reaction of dibromotriphenylphosphorane with 1,2-diols. Ring opening studies were performed with or without electrophilic activation (Lewis acids or hydrogen bonding) in order to substitute selectively one of the hydroxy function.

Full text of DOI:10.1080/10426509908546318

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