Regio- and Stereo-selective Oxidation of gem-Dimethyl Olefins via -Sigmatropic Rearrangement of Allyl Amine Oxides

DOI: 10.1246/cl.1986.2035

Source and publish data:

Chemistry Letters p. 2035 - 2038 (1986)

Update date:2022-08-03

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Authors:

Inoue, Seiichi

Iwase, Norimichi

Miyamoto, Osamu

Sato, Kikumasa

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Article abstract of DOI:10.1246/cl.1986.2035

Highly regio- and stereo-selective oxidation sequences are described for the efficient conversion of the gem-dimethyl olefin terminus of acyclic terpenes to terminal trans-allylic alcohols and trans α,β-unsaturated aldehydes.

Full text of DOI:10.1246/cl.1986.2035

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