Synthese Stereoselective des Sulfones vinyliques Z et E.

DOI: 10.1016/S0040-4039(00)87369-4

Source and publish data:

Tetrahedron Letters p. 2465 - 2468 (1982)

Update date:2022-07-30

Topics:

Authors:

Julia, Marc

Launay, Michele

Stacino, Jean-Pierre

Verpeaux, Jean-Noel

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Article abstract of DOI:10.1016/S0040-4039(00)87369-4

The condensation of α-sulphonyl carbanions with esters or with aldehydes (followed in this case by oxidation) gives β-ketosulphones.These were reduced stereoselectively into threo β-hydroxysulphones.Basic conditions have been found where the corresponding

Full text of DOI:10.1016/S0040-4039(00)87369-4

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