REGIOSPECIFIC SYNTHESIS OF α-(PHENYLTHIO)KETONES VIA RHODIUM(II) ACETATE CATALYSED ADDITION OF THIOPHENOL TO α-DIAZOKETONES

DOI: 10.1016/S0040-4039(00)87382-7

Source and publish data:

Tetrahedron Letters p. 2509 - 2512 (1982)

Update date:2022-07-30

Topics:

Authors:

McKervey, M. Anthony

Ratananukul, Piniti

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Article abstract of DOI:10.1016/S0040-4039(00)87382-7

αα-Addition of thiophenol to α-diazoketones is catalysed efficiently by rhodium(II) acetate in benzene solution at room temperature, offering a convenient regiospecific route to a variety of α-(phenylthio)ketones.

Full text of DOI:10.1016/S0040-4039(00)87382-7

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