Journal of Organometallic Chemistry p. C41 - C47 (1982)
Update date:2022-08-04
Topics:
Schenk, W. A.
Schwietzke, T.
Mueller, H.
The preparation and reactivity of two carbon disulfide complexes of tungsten, W(CO)3(R2PC2H4PR2)CS2 (R = CH3, C6H5) are described.Electrophiles (MeI, W(CO)3(R2PC2H4PR2)) add at the exocyclic sulfur, nucleophiles react with CS2 substitution (pyridine, P(OR)3), sulfur abstraction, or addition at carbon (PR3).Towards N3- the coordinated CS2 acts as a dipolarophile, where as with acetylene dicarboxylic ester it reacts as a 1,3-dipole to give a dithiocarbene derivative.
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Doi:10.1002/hlca.19420250306
(1942)Doi:10.1246/cl.1982.1211
(1982)Doi:10.1039/b618771d
(2007)Doi:10.1016/S0040-4039(00)87589-9
(1982)Doi:10.1021/ja051088p
(2005)Doi:10.1002/poc.577
(2003)
