Journal of Organometallic Chemistry p. C41 - C47 (1982)
Update date:2022-08-04
Topics:
Schenk, W. A.
Schwietzke, T.
Mueller, H.
The preparation and reactivity of two carbon disulfide complexes of tungsten, W(CO)3(R2PC2H4PR2)CS2 (R = CH3, C6H5) are described.Electrophiles (MeI, W(CO)3(R2PC2H4PR2)) add at the exocyclic sulfur, nucleophiles react with CS2 substitution (pyridine, P(OR)3), sulfur abstraction, or addition at carbon (PR3).Towards N3- the coordinated CS2 acts as a dipolarophile, where as with acetylene dicarboxylic ester it reacts as a 1,3-dipole to give a dithiocarbene derivative.
Tianjin Realet Chemical Technology Co.,Ltd.
website:http://www.realetchem.com
Contact:+86-022-58788819
Address:shuanggang industrial park
Lyrin Industrial Corporation Limited
Contact:86-731-82571800
Address:Rm 2408,Asia Economy International Building,Shaoshan Road South,Yuhua District,Changsha,Hunan,China
Contact:021-36356756
Address:Room601,Building No.14,280 Yangcheng Road,Shanghai
Contact:+86-570-4336358
Address:No.87 Building,Tianqian,Sidu Town
Nanjing Norris Pharm Technology Co., Ltd.
Contact:+86-13901585132
Address:2 Qiande Road, Jiangning sciencepark Hi-Tech Zone, Nanjing, P.R.China
Doi:10.1002/hlca.19420250306
(1942)Doi:10.1246/cl.1982.1211
(1982)Doi:10.1039/b618771d
(2007)Doi:10.1016/S0040-4039(00)87589-9
(1982)Doi:10.1021/ja051088p
(2005)Doi:10.1002/poc.577
(2003)
