STUDIES ON 1-CARBADETHIACEPHEMS, PART III: SYNTHESIS OF 2,3-DIFUNCTIONALISED 1-CARBADETHIACEPHEM DERIVATIVES

DOI: 10.1016/S0040-4039(00)87357-8

Source and publish data:

Tetrahedron Letters p. 2419 - 2422 (1982)

Update date:2022-08-05

Topics:

Authors:

Greengrass, C.W.

Hoople, D.W.T.

Nobbs, M.S.

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Article abstract of DOI:10.1016/S0040-4039(00)87357-8

A novel C(3) chlorination of p-nitrobenzyl 1-carbadethia-2-oxocephem 4-carboxylate 1 with sulphur dichloride is described.Reaction of the resulting 3-chloro-compound 8 with various thiols, and modifications at C(2) provided the title compounds.

Full text of DOI:10.1016/S0040-4039(00)87357-8

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