Generation of an N-Isocyanatoimime and its Cycloadditions leading to Sterically Stabilised Zwitterions

DOI: 10.1039/c39820000766

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 766 - 768 (1982)

Update date:2022-08-03

Topics:: Authors:

Jones, David W.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39820000766

The reaction between 1,3-dimesitylbenzofuran and 4-phenyltriazoline-3,5-dione affords a sterically stabilised zwitterion that at 110 deg C decomposes to the N-isocyanatoimine (13) which adds to olefinic and acetylenic traps to form stable zwitterions of the type (6) and (9), respectively; (9) isomerises to (10) at 110 deg C.

Full text of DOI:10.1039/c39820000766

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:C₃₅H₃₄N₂O₂

Cas No:83345-92-0

R&D Labs maybe for 83345-92-0

Shanghai Hope Chem Co., Ltd

website:http://www.hope-chem.com

Contact:86-21-58090396-805

Address:Floor 4, Building 5, No.588 Tianxiong Road, Zhoupu International Medical Zone, ShangHai, China
Shanghai shibo Chemical Co., Ltd

Contact:+86-021-60753516

Address:688 Qiushi Road, Jinshan High-tech Park, Shanghai, China,201512
Luoyang Aoda chemical Co.,Ltd.

Contact:+86-379-67518785 67516588

Address:MiaoWan industry district,YanShi City,Henan,China
MiHecb Bio-Tech Co., Ltd.

Contact:+86-0592 5353131

Address:No.56 Guani Road Software Park 2,Siming District
VanderArk International Limited

Contact:86-10-82437576

Address:Qing He

Relevant to this article

Doi:10.1021/ja00389a054
(1982)
Chemical modifications of kanamycin A synthesis of 4'-deoxy and 4'-epi-halogenodeoxy kanamycin A

Doi:10.1016/S0040-4039(00)87419-5
(1982)
A new total synthesis of the fungal toxin slaframine

Doi:10.1021/ja00389a030
(1982)
Trichloroisocyanuric Acid as an Efficient Reagent for the Synthesis of Phosphoroamidates via Atherton-Todd Reaction under Base-Free Conditions

Doi:10.1055/s-0036-1589111
(2018)
SUBSTITUENT EFFECTS ON THE DECOMPOSITION OF 1,2-DIOXETANES: A HAMMETT CORRELATION FOR SUBSTITUTED 1,6-DIARYL-1,5,7,8-TETRAOXABICYCLOY4.2.0(OCTANES

Doi:10.1016/S0040-4039(00)87500-0
(1982)
Remarkable Substituent Effects on the Chemoselectivity of Rhodium(II) Carbenoids Derived from N-(2-Diazo-3-oxobutyryl)-L-phenylalanine Esters

Doi:10.1016/0040-4020(95)00464-J
(1995)

Article Doi

Generation of an N-Isocyanatoimime and its Cycloadditions leading to Sterically Stabilised Zwitterions

DOI: 10.1039/c39820000766

Source and publish data:

Authors:

Article abstract of DOI:10.1039/c39820000766

Full text of DOI:10.1039/c39820000766

Products guided by the article

R&D Labs maybe for 83345-92-0

Relevant to this article

Hot Product