Generation of an N-Isocyanatoimime and its Cycloadditions leading to Sterically Stabilised Zwitterions

DOI: 10.1039/c39820000766

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 766 - 768 (1982)

Update date:2022-08-03

Topics:: Authors:

Jones, David W.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39820000766

The reaction between 1,3-dimesitylbenzofuran and 4-phenyltriazoline-3,5-dione affords a sterically stabilised zwitterion that at 110 deg C decomposes to the N-isocyanatoimine (13) which adds to olefinic and acetylenic traps to form stable zwitterions of the type (6) and (9), respectively; (9) isomerises to (10) at 110 deg C.

Full text of DOI:10.1039/c39820000766

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:C₃₅H₃₄N₂O₂

Cas No:83345-92-0

R&D Labs maybe for 83345-92-0

Jiangxi Dongxu Chemical Science & Technology Co.,Ltd

Contact:+86-791-86899381

Address:Nanchang, Jiangxi, China
Wuhan Fortuna Chemical Co.,Ltd

website:http://www.fortunachem.com

Contact:86-27-59207850

Address:Add: Room 2015, No.2 Building, Kaixin Mansion No.107 Jinqiao Avenue, Wuhan, China
Shanghai SMEC Trading Co., Ltd.

website:http://www.shanghaismec.com

Contact:+86-21-68811293

Address:ROOM 1101,NO.800 SHANGCHENG RD,SHANGHAI,CHINA
Shanghai Longjin Metallic Material Co., Ltd.

website:http://www.shlongjin.cn/

Contact:021-56517503,56502257

Address:No.16, Lane 555, Chengyin Road, Shanghai
Weifang Jahwa Chemical Co.,Ltd

Contact:0086-536-8897731,8897730

Address:No.5166 East Dongfeng Street,Weifang,Shandong,China

Relevant to this article

Doi:10.1021/ja00389a054
(1982)
Chemical modifications of kanamycin A synthesis of 4'-deoxy and 4'-epi-halogenodeoxy kanamycin A

Doi:10.1016/S0040-4039(00)87419-5
(1982)
A new total synthesis of the fungal toxin slaframine

Doi:10.1021/ja00389a030
(1982)
Trichloroisocyanuric Acid as an Efficient Reagent for the Synthesis of Phosphoroamidates via Atherton-Todd Reaction under Base-Free Conditions

Doi:10.1055/s-0036-1589111
(2018)
SUBSTITUENT EFFECTS ON THE DECOMPOSITION OF 1,2-DIOXETANES: A HAMMETT CORRELATION FOR SUBSTITUTED 1,6-DIARYL-1,5,7,8-TETRAOXABICYCLOY4.2.0(OCTANES

Doi:10.1016/S0040-4039(00)87500-0
(1982)
Remarkable Substituent Effects on the Chemoselectivity of Rhodium(II) Carbenoids Derived from N-(2-Diazo-3-oxobutyryl)-L-phenylalanine Esters

Doi:10.1016/0040-4020(95)00464-J
(1995)

Article Doi

Generation of an N-Isocyanatoimime and its Cycloadditions leading to Sterically Stabilised Zwitterions

DOI: 10.1039/c39820000766

Source and publish data:

Authors:

Article abstract of DOI:10.1039/c39820000766

Full text of DOI:10.1039/c39820000766

Products guided by the article

R&D Labs maybe for 83345-92-0

Relevant to this article

Hot Product