Journal of the Chemical Society. Chemical communications p. 660 (1982)
Update date:2022-08-05
Topics:
Piras, Pier Paolo
Stirling, Charles J. M.
In eliminative ring fission of cyclopropanes by the E1cB)R mechanism, gem-dimethyl substitution substantially raises ΔH*; for oxirans, which react by the E2 mechanism, this retro-Thorpe-Ingold effect is insufficient to mak
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