Oxidizing Action of Complex of N,N-Dimethylbenzylamine Oxide with SbCl5

DOI: 10.1246/bcsj.55.3035

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3035 - 3036 (1982)

Update date:2022-08-04

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Authors:

Yamamoto, Jiro

Tanioka, Yukio

Umezu, Masahiro

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Article abstract of DOI:10.1246/bcsj.55.3035

A 1:1 complex of N,N-dimethylbenzylamine oxide-SbCl5 (1) was prepared in carbon tetrachloride quantitatively.Complex 1 was found to be a better reagent for oxidation of benzoin, furoin, benzyl alchols and pinacols than the complexes pyridine N-oxide-SbCl5 and trimethylamine oxide-SbCl5.The reaction path in oxidation of benzhydrol with 1 is described.

Full text of DOI:10.1246/bcsj.55.3035

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