
Bulletin of the Chemical Society of Japan p. 3035 - 3036 (1982)
Update date:2022-08-04
Topics:
Yamamoto, Jiro
Tanioka, Yukio
Umezu, Masahiro
A 1:1 complex of N,N-dimethylbenzylamine oxide-SbCl5 (1) was prepared in carbon tetrachloride quantitatively.Complex 1 was found to be a better reagent for oxidation of benzoin, furoin, benzyl alchols and pinacols than the complexes pyridine N-oxide-SbCl5 and trimethylamine oxide-SbCl5.The reaction path in oxidation of benzhydrol with 1 is described.
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Doi:10.1021/jo00149a017
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