trans-1,3-PENTADIENE AND CYCLOBUTENE COMPLEXES OF RHODIUM(I) AND IRIDIUM(I)

DOI: 10.1016/S0022-328X(00)89070-1

Source and publish data:

Journal of Organometallic Chemistry p. 267 - 272 (1982)

Update date:2022-09-26

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Authors:

Osborne, Robert B.

Ibers, James A.

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Article abstract of DOI:10.1016/S0022-328X(00)89070-1

The generation of "MClL2" centers in THF solution (M = Ir, L = AsPh3, SbPh3; M = Rh, L = SbPh3) leads to stable η²-MCl(C5H8)L2 complexes on the addition of an excess of trans-1,3-pentadiene.For IrCl(PPh3)2, it is only possible to recover a clea

Full text of DOI:10.1016/S0022-328X(00)89070-1

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