Bull. Russ. Acad. Sci. Div. Chem. Sci. (Engl. Transl.) p. 794 - 798 (1992)
Update date:2022-08-05
Topics:
Rogovik, V. M.
Aerov, A. F.
Delyagina, N. I.
Cherstkov, V. F.
Sterlin, S. R.
German, L. S.
A study has been made of the electrochemical fluorosulfatation of perfluoro-2-alkanes in the presence of halogens, leading to the formation of fluoroaliphatic vicinal fluorosulfatohalides.The reaction proceeds as a conjugate radical addition of peroxydisulfuryl difluoride and the halogen at the double bond of the olefin; the ratio of the resulting regioisomers is determined by steric factors. Keywords: electrolysis, fluorosulfatohalogenation, stable radical.
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