Journal of Organic Chemistry p. 5099 - 5102 (1982)
Update date:2022-08-05
Topics:
Tirpak, Robin E.
Rathke, Michael W.
Trimethylsilyl enol ethers of ketones are acylated by a variety of acid chlorides in the presence of zinc chloride or antimony trichloride.The major product of this reaction is the 1,3-diketone resulting from C-acylation.Some O-acylation is observed in most cases.Yields of 1,3-diketones varied but were usually good to excellent.
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Doi:10.1246/cl.1982.1513
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(1951)Doi:10.1039/c39820000871
(1982)
