The Preparation, Variable-temperature Nuclear Magnetic Resonance Spectra, and Behaviour under Reflux Conditions of (E=S, R=Me, Ph, or CH2Ph; E=Se, R=Ph)

DOI: 10.1039/DT9820001881

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1881 - 1884 (1982)

Update date:2022-07-29

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Authors:

Broadhurst, Peter V.

Johnson, Brian F.G.

Lewis, Jack

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Article abstract of DOI:10.1039/DT9820001881

The cluster reacts with the compounds R2E2 (E=S, R=Me, Ph or CH2Ph; E=Se, S=Ph) to give the clusters (Os3(CO)10(μ-ER)2> which have been fully characterised on the basis of their spectroscopic properties.Ineach case, only one of the three possible isomers of these compounds is produced.Onheating, converts to a second isomeric form which is isostructural with the known compound whereas the compounds (E=S, R=Ph, or CH2Ph; E=Se, R=Ph) give small yields of (E=S,or Se) and (E=S or Se, R=Ph).

Full text of DOI:10.1039/DT9820001881

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