The Preparation, Variable-temperature Nuclear Magnetic Resonance Spectra, and Behaviour under Reflux Conditions of (E=S, R=Me, Ph, or CH2Ph; E=Se, R=Ph)

DOI: 10.1039/DT9820001881

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1881 - 1884 (1982)

Update date:2022-07-29

Topics:

Authors:

Broadhurst, Peter V.

Johnson, Brian F.G.

Lewis, Jack

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9820001881

The cluster reacts with the compounds R2E2 (E=S, R=Me, Ph or CH2Ph; E=Se, S=Ph) to give the clusters (Os3(CO)10(μ-ER)2> which have been fully characterised on the basis of their spectroscopic properties.Ineach case, only one of the three possible isomers of these compounds is produced.Onheating, converts to a second isomeric form which is isostructural with the known compound whereas the compounds (E=S, R=Ph, or CH2Ph; E=Se, R=Ph) give small yields of (E=S,or Se) and (E=S or Se, R=Ph).

Full text of DOI:10.1039/DT9820001881

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[Os₃(CO)10(SC₆H₅)2]

Cas No:83971-69-1

R&D Labs maybe for 83971-69-1

Changyi Xinxing Technology Development Co., Ltd.

Contact:0086-510-86651065(Time Zone:8),86651656

Address:94 Yingbinxilu WestRoad, Huangtu Town, Jiangyin City, Jiangsu, China
Taizhou Chemedir Biopharm-tech Co., Ltd

Contact:+86 523 86200218

Address:G09, No. 1 Avenue China Medical City, Taizhou,Jiangsu, China
Shandong Dayi Chemical Co., Ltd.

website:http://www.dayi.com.cn

Contact:+86- 535-7388728. 15306386031

Address:No 1 Danya west road, Laiyang City, Shandong province
Tianjin Tongde Biological Technology Co., Ltd.

Contact:86-22-23309138

Address:Room 402, bulidingE3 Detection certification park, XiQingDistrict, Tianjin City
Deer Chemicals Co., Ltd.

Contact:+86-13666670345

Address:Agricultural Development Zone, Haining, Jiaxing, Zhejiang

Relevant to this article

Chemoenzymatic stereoconvergent synthesis of 3-O-benzoyl azidosphingosine

Doi:10.1016/S0957-4166(02)00201-X
(2002)
Facile single or double C-H bond activation on η ²-platinum-complexed acetylenes by interaction with [cis-PtR ₂S₂] and [cis-PtR₂(CO)S] (R = C ₆F₅, S = Thf)

Doi:10.1021/om049208+
(2005)
Redox-Neutral ortho Functionalization of Aryl Boroxines via Palladium/Norbornene Cooperative Catalysis

Doi:10.1016/j.chempr.2019.02.005
(2019)
Gas phase study of the kinetics of formation and dissociation of Fe(CO)₄L and Fe(CO)₃L₂ (L = C₂H₄ and C₂F₄)

Doi:10.1021/jp970275+
(1997)
Synthesis and thermal properties of twin dimers containing cyanostilbene derivatives as a mesogenic group

Doi:10.1080/15421400490478326
(2004)
Discrepancy between the spin distribution and the magnetic ground state for a triaminoxyl substituted triphenylphosphine oxide derivative

Doi:10.1002/chem.200400656
(2005)

Article Doi