Co-ordination Chemistry of Higher Oxidation States. Part 3. Palladium(IV) Complexes with Neutral Unidentate Ligands

DOI: 10.1039/DT9820001895

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1895 - 1898 (1982)

Update date:2022-08-04

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Authors:

Gulliver, David J.

Levason, William

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Article abstract of DOI:10.1039/DT9820001895

Oxidation of with the corresponding halogen (X2) in carbon tetrachloride gave octahedral palladium(IV) anions n3, X=Cl; L=PEt2Ph, X=Br>.Attemps toprepare analogues with L=SbMe3, TeMe2, or dmso (dimethyl sulphoxide) failed.Neutral palladium (IV) complexes trans- (L=NMe3, Py, PPrⁿ₃, or AsMe2Ph, X= Cl; L=NMe3, X= Br) have been obtained from trans- and X2.The complexes were characterised by i.r. and electronic spectroscopy, and conductivity measurements, and their thermal decomposition examined by t.g.a.

Full text of DOI:10.1039/DT9820001895

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