Journal of Organometallic Chemistry p. C64 - C66 (1982)
Update date:2022-08-04
Topics:
Kobayashi, Toshiaki
Tanaka, Masato
Aryl, hetero-aryl, and vinylic halides react with carbon monoxide (40 atm pressure or less) and a secondary amine at 60-100 deg C in the presence of a catalytic amount of palladium compound to form α-ketoamides, in addition to simple amides as by-products.When a primary amine was used in place of a secondary one, an imine of the α-ketoamide was readily obtained.
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