PALLADIUM(II)-CATALYZED DOUBLE CARBONYLATION OF ORGANIC HALIDES IN THE PRESENCE OF AMINES: α-KETOAMIDE SYNTHESIS

DOI: 10.1016/S0022-328X(00)85589-8

Source and publish data:

Journal of Organometallic Chemistry p. C64 - C66 (1982)

Update date:2022-08-04

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Authors:

Kobayashi, Toshiaki

Tanaka, Masato

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Article abstract of DOI:10.1016/S0022-328X(00)85589-8

Aryl, hetero-aryl, and vinylic halides react with carbon monoxide (40 atm pressure or less) and a secondary amine at 60-100 deg C in the presence of a catalytic amount of palladium compound to form α-ketoamides, in addition to simple amides as by-products.When a primary amine was used in place of a secondary one, an imine of the α-ketoamide was readily obtained.

Full text of DOI:10.1016/S0022-328X(00)85589-8

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