A Facile Synthesis of 2,3-Dihydroxyketones from 1,2-Diketones and Aldehydes Using Samarium Diiodide

DOI: 10.1246/cl.1993.959

Source and publish data:

Chemistry Letters p. 959 - 962 (1993)

Update date:2022-08-03

Topics:

Authors:

Miyoshi, Norikazu

Takeuchi, Seiji

Ohgo, Yoshiaki

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1993.959

In the presence of samarium diiodide, 1,2-diketones react with aldehydes to afford the corresponding 2,3-dihydroxyketones in good yields with moderate diastereoselectivity.The reaction of unsymmetrical 1,2-diketones with aldehydes gives the products with high regioselectivities.

Full text of DOI:10.1246/cl.1993.959

Products guided by the article

Product name:(4R,5S)-4-Ethyl-4,5-dihydroxy-7-phenyl-heptan-3-one

Cas No:84104-19-8

R&D Labs maybe for 84104-19-8

GIHI CHEMICALS CO.,LIMITED

Contact:+86-571-86217390

Address:No.567 Dengcai Street,Sandun,Westlake District,Hangzhou310030,Zhejiang,China.
Taizhou Huading Chemical Co.,Ltd(expird)

Contact:+86-576-88583898

Address:Economic&Technology development zone,Taizhou City,Zhejiang Province,China
Tianjin Ingenochem Technology Co.,Ltd

Contact:+86-22-23677060

Address:Hitech Green Industry Park K2-9-602, Nankai district
Hangzhou Showland Technology Co., Ltd.

Contact:86-571-88920516

Address:ROOM2118,NO.553,WENSAN ROAD,HANGZHOU,CHINA
Shijiazhuang Haitian Amino Acid Co., Ltd.

Contact:+86-311-88908111

Address:Shijiazhuang Hebei province,China

Relevant to this article

SYNTHESIS OF ARYL 4(5)-IMIDAZOLYL KETONES

Doi:10.1007/BF00474010
(1991)
Platinum(II) Complexes of Nitroimidazoles: Synthesis, Characterisation, and X-Ray Crystal Structures of cis-dichlorobis<1-(2'-hydroxyethyl)-2-hydroxymethyl-5-nitroimidazole>platinum(II) and trans-dichlorobis<1-(2'-hydroxy-3'-methoxypropyl)-2-nitroimidazole>platinum(II)

Doi:10.1039/DT9850000795
(1985)
Nonhomogeneous Phase Effect on the Generation of Carbene Radical Anions in the Birch-Type Reduction of Bis(gem-dihalocyclopropyl) Compounds

Doi:10.1021/jo00152a047
(1983)
Titanium complexes with chiral amino alcohol ligands: Synthesis and structure of complexes related to hydroamination catalysts

Doi:10.1016/j.ica.2004.09.051
(2005)
Functional derivatives of (bromomethyl)phosphonic acid

Doi:10.1007/s11176-005-0131-3
(2004)
Doi:10.1039/jr9340000325
(1934)

Article Doi