A Facile Synthesis of 2,3-Dihydroxyketones from 1,2-Diketones and Aldehydes Using Samarium Diiodide

DOI: 10.1246/cl.1993.959

Source and publish data:

Chemistry Letters p. 959 - 962 (1993)

Update date:2022-08-03

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Authors:

Miyoshi, Norikazu

Takeuchi, Seiji

Ohgo, Yoshiaki

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Article abstract of DOI:10.1246/cl.1993.959

In the presence of samarium diiodide, 1,2-diketones react with aldehydes to afford the corresponding 2,3-dihydroxyketones in good yields with moderate diastereoselectivity.The reaction of unsymmetrical 1,2-diketones with aldehydes gives the products with high regioselectivities.

Full text of DOI:10.1246/cl.1993.959

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