Journal of Organometallic Chemistry p. 215 - 220 (1982)
Update date:2022-08-05
Topics:
Rybinskaya, M. I.
Kaganovich, V. S.
Kudinov, A. R.
A number of symmetrical and unsymmetrical bis-arene-ruthenium cations has been prepared and their reduction with sodium borohydride studied.Hydride hydrogen is shown to add preferentially to the less alkylated ring.The conditions are established, which allow the preparation of a new, previously unknown, cationic complex of arene-cyclohexadienyl-ruthenium by stepwise addition of hydride hydrogen.
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