A CONVENIENT METHOD FOR THE SYNTHESIS OF HOMOALLYL ALCOHOL USING A NEW DESULFONYLATION METHOD

DOI: 10.1246/cl.1982.1331

Source and publish data:

Chemistry Letters p. 1331 - 1334 (1982)

Update date:2022-08-05

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Authors:

Kotake, Hiroshi

Yamamoto, Taku

Kinoshita, Hideki

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Article abstract of DOI:10.1246/cl.1982.1331

2-Tosyl homoallyl alcohol obtained by the reaction of allylic p-tolyl sulfone with aldehyde was found to be easily desulfonylated to homoallyl alcohol by the use of Pd(PPh3)4 as a catalyst and hydride ion as a nucleophile, without any side reactions.

Full text of DOI:10.1246/cl.1982.1331

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