Stannous Chloride Mediated Formation of (9-Anthryl)methyl Dimers from (Halogenomethyl)anthracenes. Ground-State and Adiabatic Excited-State Reversibility of Intramolecular Cycloadditions

DOI: 10.1021/jo01311a001

Source and publish data:

Journal of Organic Chemistry p. 4549 - 4555 (1980)

Update date:2022-07-30

Topics:

Authors:

Becker, Hans-Dieter

Andersson, Kjell

Sandros, Kjell

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Article abstract of DOI:10.1021/jo01311a001

9-(Halogenomethyl)anthracenes react with stannous chloride dihydrate in dioxane solution to give tetrabenzotetracyclotetradecatetraenes ("lepidopterenes") in excellent yields. The involvement of <(9-anthryl)methyl>tin trihalides in the reaction is suggest

Full text of DOI:10.1021/jo01311a001

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