Application of the Catalytic Two-Phase System to Carbanionic Reactions of Allyl Sulfones

DOI: 10.1021/jo00154a042

Source and publish data:

Journal of Organic Chemistry p. 910 - 912 (1983)

Update date:2022-08-05

Topics:

Authors:

Jonczyk, Andrzej

Radwan-Pytlewski, Tadeusz

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00154a042

Allyl sulfones are easily converted into carbanions in the presence of concentrated aqueous NaOH solution and a quaternary ammonium catalyst.These carbanions readily react with alkyl halides, electrophilic alkenes, or perchloroalkanes.

Full text of DOI:10.1021/jo00154a042

Products guided by the article

Product name:2-methyl-4,6-di(phenylsulphonyl)-2-hexene

Cas No:84602-92-6

R&D Labs maybe for 84602-92-6

Onlychem (Jinan)Biotech Co.,Ltd

Contact:86-531-83175885

Address:No. 44, Honglou South Road, Jinan,China
SHANGHAI RC CHEMICALS CO.,LTD.

website:http://www.rcc.net.cn

Contact:+86-21-50322175

Address:Rm1415 Yinqiao Masion No.58 Jinxin Road Pudong Shanghai China
Jinzhou Jiutai Pharmaceutical Co.,Ltd

Contact:+86-0416-5179890

Address:No.41, Taianli, Taihe District, Jinzhou, Liaoning
Suzhou SuKaiLu Chemical Technology Co., Ltd.

Contact:+86-512-62766020

Address:Floor 4, Building 1, Xinyi Pharmaceutical Valley Wisdom Industrial Park, 415 Changyang Street, Suzhou Industrial Park, Jiangsu Province
Synchemie Co., Ltd.

website:http://www.synchemie.com/

Contact:+86-574-87642758

Address:Room 901, Yinyi Bund Building， 132 Renmin Road

Relevant to this article

Stereoselective Csp³?Csp² Cross-Couplings of Chiral Secondary Alkylzinc Reagents with Alkenyl and Aryl Halides

Doi:10.1002/anie.201910397
(2020)
Aza-peterson olefinations: Rapid synthesis of (E)-alkenes

Doi:10.1055/a-1493-6670
(2021)
N,S,O-Containing organic ligands based on salicylaldehyde and 2-thiosubstituted ethylamines and their complexes with Co^II, Ni ^II, and Cu^II

Doi:10.1007/s11172-007-0210-1
(2007)
Geminal bis(sulfoximine)s: Synthesis and applications in asymmetric catalysis

Doi:10.1002/adsc.200404164
(2004)
Development of an Efficient Dual-Action GST-Inhibiting Anticancer Platinum(IV) Prodrug

Doi:10.1002/cmdc.201800105
(2018)
Fluorine-containing heterocycles: X. Acetoacetamides in the synthesis of fluorine-containing chromone

Doi:10.1023/B:RUJO.0000045899.90635.62
(2004)

Article Doi