Bulletin of the Chemical Society of Japan p. 3675 - 3676 (1982)
Update date:2022-08-02
Topics: Aminolysis
Acher, Francine
Wakselman, Michel
Nucleophilic attack of a carboxylate salt on a five membered phosphonic or phosphinic ester followed by an intramolecular acyl transfer reaction gives a substituted aryl ester.Due to the intramolecular base catalysis of a neighbouring P=O group the bimolecular aminolysis of this ester is a fast process.
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