Some di- and trinuclear zinc complexes: Anion induced complex formation

Article abstract of DOI:10.1080/00945710009351793

Complexes of N,N'-bis(salicylidene)-1,3-diaminopropane, an ONNO type ligand, with ZnX₂ (X = AcO^-, NO₃₊, Cl^-, Br^-, I^-) salts were prepared Molecular structures of these complexes were identified using elemental analyses, IR spectrometry and X-ray diffraction techniques. It has been observed that the reactions between zinc ions and the said ligand tend to produce polynuclear complexes and depending on the anion present either di-or trinuclear complexes are formed. Thus, it can be deduced from the results presented in this article that trinuclear complexes form when the zinc salt used was the acetate or nitrate and dinuclear complexes form if the anion in the zinc salt is a halogen.

Full text of DOI:10.1080/00945710009351793

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Synthesis and Reactivity in
Inorganic and Metal-Organic
Chemistry
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Some DI- and Trinuclear Zinc
Complexes: Anion Induced
Complex Formation
Orhan Atakol a , Hasan Nazir a , Mecit Aksu a , Cengiz
Anci b , Filiz Ercan b & Burhanettin Çiçek c
a Chemistry Department, Faculty of Sciences ,
University of Ankara , Tandogan, 06100, Ankara,
Turkey
b Department of Engineering Physics , Hacettepe
University , Beytepe, 06532, Ankara, Turkey
c Chemical Engineering Department , University of
Ankara , Tandogan, 06100, Ankara, Turkey
Published online: 23 Apr 2008.
To cite this article: Orhan Atakol , Hasan Nazir , Mecit Aksu , Cengiz Anci , Filiz
Ercan & Burhanettin Çiçek (2000) Some DI- and Trinuclear Zinc Complexes: Anion
Induced Complex Formation, Synthesis and Reactivity in Inorganic and Metal-Organic
Chemistry, 30:4, 709-718, DOI: 10.1080/00945710009351793
To link to this article: http://dx.doi.org/10.1080/00945710009351793
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