Journal of Organic Chemistry p. 912 - 914 (1983)
Update date:2022-08-05
Topics:
Hiyama, Tamejiro
Obayashi, Michio
Mori, Ichiro
Nozaki, Hitosi
The Si-Si bond of disilanes is found to be cleaved by tetrabutylammonium fluoride (TBAF) in hexamethylphosphoric triamide to produce metal-free silylanion and triorganosilyl fluoride.The disilane/TBAF reagent was studied spectrometrically.Sythetic application of the reagent with a catalytic amount of TBAF is illustrated by the reaction with aldehydes and 1,3-dienes.
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