The Favorskii-type Rearrangement of 3-Bromo-β-ionone with Sodium Ethoxide

DOI: 10.1246/bcsj.55.3655

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3655 - 3656 (1982)

Update date:2022-08-05

Topics:

Authors:

Nanasawa, Masato

Kamogawa, Hiroyoshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.55.3655

The reaction of 3-bromo-β-ionone with sodium ethoxide afforded ethyl 4-(2,6,6-trimethyl-2-cyclohexenylidene)butyrate by a Favorskii-type rearrangement, accompanied by double-bond migration, while with sodium phenoxide or diethyl amine, substitution produc

Full text of DOI:10.1246/bcsj.55.3655

Products guided by the article

Product name:3-Buten-2-one, 4-(2,6,6-trimethyl-3-phenoxy-1-cyclohexen-1-yl)-, (E)-

Cas No:84817-82-3

R&D Labs maybe for 84817-82-3

Weihao Chemtech (ChangZhou) Co., Ltd.(expird)

Contact:051989185693

Address:NO 217 huangshan Rd ,Changzhou
Shanghai Bocimed Pharmaceutical Co., Ltd.

website:http://www.bocimed.com

Contact:+86-21-68861632

Address:Building 1, Lane 647, Songtao Road, Zhangjiang High-Tech Park, Shanghai
Xi'an Unique Electronic and Chemical Co., Ltd.

Contact:+86-029-88238008

Address:1703# B BUILDING WEST ELECTRONIC ZONE, XI'AN, CHINA
RongCheng K&S Chemical Co.,Ltd

Contact:0631-7336369

Address:rongcheng ,shandong province china
Beijing Mashi Fine Chemical Co.,Ltd.

Contact:+86-10-61271592

Address:Room 506, Section B, Kaichi Mansion, Industrial Development

Relevant to this article

Evaluation of zirconium and hafnium complexes that contain the electron-withdrawing diamido/donor ligand [(2,6-Cl₂C ₆H₃NCH₂CH₂)₂NCH ₃]^2- for the polymerization of 1-he

Doi:10.1021/om040113h
(2005)
Ruthenium-Catalyzed Tandem Carbene/Alkyne Metathesis/N-H Insertion: Synthesis of Benzofused Six-Membered Azaheterocycles

Doi:10.1021/acs.orglett.0c00596
(2020)
Ruthenium-catalyzed stereoselective intramolecular carbenoid C-H insertion for β- and γ-lactam formations by decomposition of α-diazoacetamides

Doi:10.1021/ol050003m
(2005)
Total synthesis of (+)-allocyathin B₂

Doi:10.1021/ja0435586
(2005)
Synthesis and characterization of ionic organotin compounds [R ₂SnCl₂(2-quin)]^-(HNEt₃)⁺ and crystal structures of [(2,4-Cl₂-C₆H₃CH ₂)₂SnCl₂(2-quin)]^-(HNEt ₃)⁺

Doi:10.1016/j.jorganchem.2004.11.003
(2005)
3,6-Bis(2′-pyridyl)pyridazine (L) and its deprotonated form (L H ⁺)^- as ligands for {(acac)(2)Ruⁿ⁺} or {(bpy)₂Ru^m+}: Investigation of mixed valency in [{(acac)(2)Ru}(2)(μ-L - H⁺)]⁰ and [{(bpy)₂Ru}₂(μ-L - H⁺)]⁴⁺ by spectroelectrochemistry and EPR

Doi:10.1039/b417530a
(2005)

Article Doi