Stereochemistry of hydroxylation during the conversion of α-ketoisocaproate to β-hydroxyisovalerate by 4-hydroxyphenylpyruvate dioxygenase

DOI: 10.1016/S0960-894X(96)00489-1

Source and publish data:

Bioorganic and Medicinal Chemistry Letters p. 2721 - 2724 (1996)

Update date:2022-08-05

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Authors:

Adlington, Robert M.

Baldwin, Jack E.

Crouch, Nicholas P.

Lee, Meng-Huee

MacKinnon, Colin H.

Paul, Diana R.

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Article abstract of DOI:10.1016/S0960-894X(96)00489-1

4-Hydroxyphenylpyruvate dioxygenase catalyzes the oxidative decarboxylation and hydroxylation of α-ketoisocaproate 1 to β-hydroxyisovalerate 2 with retention of configuration during the hydroxylation step.

Full text of DOI:10.1016/S0960-894X(96)00489-1

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