Journal of Organic Chemistry p. 1796 - 1801 (2005)
Update date:2022-08-05
Topics:
Garcia Ruano, Jose L.
Fernandez-Ibanez, M. Angeles
Maestro, M. Carmen
Rodriguez-Fernandez, M. Mercedes
(Chemical Equation Presented) The reduction of δ-ketosulfoxides constitutes the first evidence of the efficiency of the sulfinyl group to control the stereoselectivity of 1,5-asymmetric induction processes. The use of DIBAL/Yb(OTf)3 or L-Selectride as the reducing agents provides δ-hydroxysulfoxides with the opposite configuration at the hydroxylic carbon in a highly stereoselective way.
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