CINETIQUE ET MECANISME DE LA REACTION DE PROTOTROPIE DES COMPOSIES PROPARGYLIQUES, ALLENIQUES ET PROPYNYLIQUES PORTANT UN HETEROATOME (COLONNE Vb ET VIb)

Article abstract of DOI:10.1016/0040-4020(82)85159-4

A detailed kinetic study of the prototropic rearrangement of the system RMCH2-C<*>CH<*>RM-CH=C=CH2<*>RM-C<*>C-CH3 where M=NR, O, S, Se is presented.Using deuterated substrates the nature of the reactive intermediates and, in the case of M=S, the activatio