Tetrahedron Letters p. 4171 - 4174 (1982)
Update date:2022-08-04
Topics:
Lehousse, C.
Haddad, M.
Barrans, J.
The reaction of Mes-PCl2 with several amines gives new compounds, oligomers of Mes-P=N-R.Chemical properties of these oligomers are investigated : action of alcohols and disubstituted amines (XH) gives Mes-PHX(=NR), the formation of which are only consistent with the presence of a dicoordinated phosphorus compound, Mes-P=N-R, in equilibrium with a tetramer (-P(Mes)-N(R)-)4.
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