Synlett p. 1730 - 1732 (2002)
Update date:2022-08-03
Topics:
Cooper, Tracey S.
Larigo, Alexander S.
Laurent, Pierre
Moody, Christopher J.
Takle, Andrew K.
Addition of organometallic reagents to O-(1-phenylbutyl)benzyloxyacetaldoxime in the presence of boron trifluoride diethyl etherate is highly diastereoselective; the resulting hydroxylamines are readily converted into protected 1,2-aminoalcohols and 2-hydroxymethyl nitrogen heterocycles, including the iminosugar 1,4-dideoxy-1,4-imino-D-ribitol, in high enantiomeric excess.
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