The Directed Ortho Lithiation of O-Aryl Carbamates. An Anionic Equivalent of the Fries Rearrangement

DOI: 10.1021/jo00159a040

Source and publish data:

Journal of Organic Chemistry p. 1935 - 1937 (1983)

Update date:2022-08-05

Topics:

Authors:

Sibi, Mukund P.

Snieckus, Victor

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00159a040

Ortho-Lithiated O-aryl carbamates 3 constitute new synthetic intermediates which by treatment with a variety of electrophiles lead to ortho-substituted carbamates 4 and by rearrangement provide salicylamides 6.

Full text of DOI:10.1021/jo00159a040

Products guided by the article

Product name:Diethyl-carbamic acid 2-(bis-trimethylsilanyl-methyl)-phenyl ester

Cas No:85630-38-2

R&D Labs maybe for 85630-38-2

Phytomarker Ltd.(expird)

Contact:+86-22-26358246

Address:601-4-20, Fujiayuan, Tiantai Road, Hebei District, Tianjin, China
Weihao Chemtech (ChangZhou) Co., Ltd.(expird)

Contact:051989185693

Address:NO 217 huangshan Rd ,Changzhou
Esuccess Material Limited

Contact:852-29282288

Address:HONGKONG
Shandong Jusage Technology Co.,Ltd.

Contact:86-13406130167

Address:No.20,North Ride No.9 Road, Guangrao Economic Development Zone, Shandong Province
Taiwan Surfactant Corp.

Contact:886 2 2541 0022

Address:8 Fl., No. 11, Sec. 1, Chung Shan North Rd., Taipei, Taiwan R.O.C.

Relevant to this article

Doi:10.1039/jr9360001649
(1936)
NMR characterization of hydrate and aldehyde forms of imidazole-2- carboxaldehyde and derivatives

Doi:10.1021/jo902588s
(2010)
Doi:10.1021/ja01616a044
(1955)
Synthesis, evaluation, and CoMFA study of fluoroquinophenoxazine derivatives as bacterial topoisomerase IA inhibitors

Doi:10.1016/j.ejmech.2016.09.053
(2017)
Cobalt-catalyzed reductive carboxylation on α,β-unsaturated nitriles with carbon dioxide

Doi:10.1246/cl.131163
(2014)
Doi:10.1002/hlca.193702001130
(1937)

Article Doi