The Directed Ortho Lithiation of O-Aryl Carbamates. An Anionic Equivalent of the Fries Rearrangement

DOI: 10.1021/jo00159a040

Source and publish data:

Journal of Organic Chemistry p. 1935 - 1937 (1983)

Update date:2022-08-05

Topics:

Authors:

Sibi, Mukund P.

Snieckus, Victor

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Article abstract of DOI:10.1021/jo00159a040

Ortho-Lithiated O-aryl carbamates 3 constitute new synthetic intermediates which by treatment with a variety of electrophiles lead to ortho-substituted carbamates 4 and by rearrangement provide salicylamides 6.

Full text of DOI:10.1021/jo00159a040

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