Synthesis of four possible intermediates after secologanin on the biosynthesis of the oleoside-, 10-hydroxyoleoside- and ligustaloside-type glucosides in oleaceous plants

DOI: 10.1248/cpb.46.900

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 900 - 905 (1998)

Update date:2022-09-26

Topics:

Authors:

Kuwajima, Hiroshi

Tanahashi, Takao

Inoue, Kenichiro

Inouye, Hiroyuki

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1248/cpb.46.900

To examine the biosynthetic pathways from secologanin to three types of secoiridoid glucosides characteristic of oleaceous plants, synthesis of two respective stereoisomers at C-8 of 8,10-epoxysecologanin and -secoxyloganin was established and their deuterium-labeled analogues were prepared.

Full text of DOI:10.1248/cpb.46.900

NII-Electronic Library Service

Products guided by the article

Product name:Acetic acid (3R,4S,5R,6R)-4,5-diacetoxy-6-acetoxymethyl-2-((3S,4S,4aS)-4-(R)-oxiranyl-8-oxo-4,4a,5,6-tetrahydro-3H,8H-pyrano[3,4-c]pyran-3-yloxy)-tetrahydro-pyran-3-yl ester

Cas No:85647-49-0

R&D Labs maybe for 85647-49-0

Suzhou Sibian Chemical Technology Co., Ltd

website:http://www.sibianpharm.com

Contact:+8618169181984,+8618013186906

Address:Room1404,BuildingA,Jiabao Square No.323 Baodai East Road,Wuzhong District,Suzhou Jiangsu China (215128)
ShangHai Original Economy-Trade Develop Co.,Ltd.,

Contact:86-21-68552131

Address:shanghai
Valiant Fine Chemicals Co., Ltd.

Contact:+86 535 6101878/6374484

Address:11 Wuzhishan Rd.,YTETDZ,Yantai,264006,Shandong,China
Greenutra Resource Inc

website:http://www.greenutra.cn

Contact:0086-411-39553357

Address:No. 7-1-1802, Huizhi Garden,Ocean Square,Dalian, 116033, China
Guangzhou Reachin Chemical Co., Ltd

Contact:+86-20-37087379 ext.604

Address:A122C-1, Tianyuan Plaza, 401 Tianyuan Rd., Tianhe, Guangzhou, China

Relevant to this article

Stereochemistry of the macrocyclization and elimination steps in taxadiene biosynthesis through deuterium labeling

Doi:10.1021/jo0502091
(2005)
Doi:10.1139/v73-225
(1973)
Thermolysis of Benzopyranone-Indenone Adducts: A New Route to the C-Nor-D-Homo Steroid Skeleton

Doi:10.1021/jo00161a011
(1983)
Doi:10.1007/BF03020731
(1945)
Doi:10.1039/jr9520000013
(1952)
Design, synthesis, DFT study and antifungal activity of the derivatives of pyrazolecarboxamide containing thiazole or oxazole ring

Doi:10.1016/j.ejmech.2018.02.036
(2018)

Article Doi