Chemistry Letters p. 405 - 408 (1983)
Update date:2022-08-05
Topics: Cleavage Chemoselectivity Sulfides iodotrimethylsilane Trimethylsilyl trifluoromethanesulfonate
Hosomi, Akira
Sakata, Yasuyuki
Sakurai, Hideki
Reactions of α-heteroatom substituted ethers and related compounds (R1R2CXY; X, Y = RO, RS and Cl) with silyl enol ethers and ketene silyl acetals took place in the presence of iodotrimethylsilane (Ia) and trimethylsilyl triflate (Ib) as a catalyst and factors influencing the activation of the heteroatom by I were examined.
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Doi:10.1021/ja01337a049
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