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Stereoselective Synthesis of a (5R,6S)-6--2-aryloxypenem

DOI: 10.1039/c39830001005

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1005 - 1006 (1983)

Update date:2022-08-03

Topics:

Authors:

Cooke, Michael D.Cooke, Michael D.

Moore, Kevin W.Moore, Kevin W.

Ross, Barry C.Ross, Barry C.

Turner, Susan E.Turner, Susan E.

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Article abstract of DOI:10.1039/c39830001005

(5R,6S)-<(R)-1-Hydroxyethyl>-2-aryloxypenems can be synthesised through hydroxy group directed chlorinolysis of the (3S,4R)-3-<(R)-1-hydroxyethyl>-4-ethylthioazetidinone (8) to the (4S)-4-chloroazetidinone (9) with subsequent cyclisation.

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Products guided by the article

Product name:4-Nitrobenzyl 2-[3(S)-{1(R)-dimethyl-(2-methylprop-2-yl)silyloxyethyl}-4(R)-ethylthioazetidin-2-on-1-yl]-3-(4-chlorophenoxy)-3-trimethylacetylthio propenoate

Cas No:85768-31-6

85768-31-6

R&D Labs maybe for 85768-31-6

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