PROTONATION OF TERTIARY PHOSPHINE PLATINUM(0) COMPLEXES BY AMMONIUM ION. CHARACTERIZATION AND SOME REACTIONS OF THE RESULTING HYDRIDES

DOI: 10.1016/S0022-328X(00)98622-4

Source and publish data:

Journal of Organometallic Chemistry p. 303 - 310 (1983)

Update date:2022-08-05

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Authors:

Goel, Ram G.

Srivastava, Ramesh C.

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Article abstract of DOI:10.1016/S0022-328X(00)98622-4

The platinum(0) complexes Pt(PR3)2 (R3=(t-Bu)3 and (t-Bu)2Ph) react readily with the ammonium salts NH4X (X=PF6 and ClO4) to give the cationic ammine hydrides trans-X.Reaction of Pt(PPH3)3 with NH4PF6 affords PF6.The ammine hyd

Full text of DOI:10.1016/S0022-328X(00)98622-4

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Product name:{PtH(CO)(P(C(CH₃)3)2(C₆H₅))2}⁽¹⁺⁾*PF₆^(1-)={PtH(CO)(P(C(CH₃)3)2(C₆H₅))2}PF₆

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