Tetrahedron Letters p. 7475 - 7478 (1995)
Update date:2022-08-05
Topics:
Matano, Yoshihiro
Yoshimune, Masanori
Suzuki, Hitomi
Reaction of triarylbismuth difluorides 1 with allyltrimethylsilane 2 in CH2Cl2 in the presence of BF3·OEt2 at low temperature generates allyltriarylbismuthonium compound 3 as a pale yellow solution, in which aromatic hydrocarbons and ethers, triphenylphosphine, dimethyl sulfide, p-toluenesulfinate, and thiophenol are all readily allylated to afford the corresponding allyl derivatives in moderate to good yields.
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