Preparation and X-Ray Crystal Structure of 3,3,5,5,9,9,11,11-Octaphenyl-1,7-di-λ4-thia-2,4,6,8,10,12-hexa-aza-3,5,9,11-tetra-λ5-phosphabicyclododecahexaene: a Twelve-membered Inorganic Heterocycle with a Transannular Sulphur-S

DOI: 10.1039/c39830000186

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 186 - 187 (1983)

Update date:2022-08-04

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Authors:

Chivers, Tristram

Rao, M. N. Sudheendra

Richardson, John F.

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Article abstract of DOI:10.1039/c39830000186

The reaction of the six-membered ring compound (Ph2PN)2NSCl with triphenylantimony in acetonitrile produces (Ph2PN)4(SN)2 shown by X-ray crystallography to consist of a twelve-membered ring with a transannular sulphur-sulphur bond.

Full text of DOI:10.1039/c39830000186

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