Tetrahedron Letters p. 1041 - 1044 (1983)
Update date:2022-08-03
Topics:
Sato, Fumie
Watanabe, Hiroshi
Tanaka, Youichi
Yamaji, Takafumi
Sato, Masao
Hydromagnesiation of 1-trimethylsilyl-1-alkynes with isobutylmagnesium bromide in the presence of a catalytic amount of Cp2TiCl2 followed by treatment of the resulting vinyl Grignard reagents with alkyl iodides and copper iodide affords (Z)-1,2-dialkyl-vinylsilanes in excellent yields.The utility of the reaction sequence is illustrated by a simple synthesis of 7(E)-dodecenyl acetate and dihydrojasmone.
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