Tetrahedron Letters p. 1041 - 1044 (1983)
Update date:2022-08-03
Topics:
Sato, Fumie
Watanabe, Hiroshi
Tanaka, Youichi
Yamaji, Takafumi
Sato, Masao
Hydromagnesiation of 1-trimethylsilyl-1-alkynes with isobutylmagnesium bromide in the presence of a catalytic amount of Cp2TiCl2 followed by treatment of the resulting vinyl Grignard reagents with alkyl iodides and copper iodide affords (Z)-1,2-dialkyl-vinylsilanes in excellent yields.The utility of the reaction sequence is illustrated by a simple synthesis of 7(E)-dodecenyl acetate and dihydrojasmone.
View MoreContact:+86-371-55981030
Address:Room 1571, Macalline Soho, No.1, Shangdu Road, Zhengzhou, Henan
Contact:+86-571-87010026
Address:202, Zhenhua Road,
Taizhou Elitechemie MediPharma Technology Co.,Ltd.
Contact:+86-523-86810021
Address:Building G14,NO.1 Avenue,China Medical City, Taizhou, Jiangsu,China
Jurong Huaheng Natural Biological Products Factory
website:http://www.risebiochem.com
Contact:+86-13921007726
Address:Chuncheng town,Jurong city,Jiangsu province,China
Shenzhen JYMed Technology Co.,Ltd.
website:http://www.jymedtech.com
Contact:+86-755-26612112
Address:1#8,9/F, Biomedicine innovation Industrial Park, No.14, Jinhui Road, Pingshan Sistrict, Shenzhen, China
Doi:10.1016/j.tet.2005.06.084
(2005)Doi:10.1021/ol0515311
(2005)Doi:10.1016/j.molstruc.2013.08.032
(2013)Doi:10.1016/0022-328X(83)85026-8
(1983)Doi:10.1149/1.2116687
(2005)Doi:10.1007/s11172-007-0054-8
(2007)