Stereoselective Synthesis of (E)-2-(1-Hydroxyalkyl)alk-2-enenitriles via (Z)-1-Cyanoalk-1-enyl Anion Intermediates

DOI: 10.1039/c39830000170

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 170 - 171 (1983)

Update date:2022-07-31

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Authors:

Sato, Yoshiro

Hitomi, Kyoko

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Article abstract of DOI:10.1039/c39830000170

Fluoride ion-induced desilylation of (E)-2-trimethylsilylalk-2-enenitriles affords (Z)-1-cyanoalk-1-enyl anion intermediates, which are trapped by carbonyl compounds to give (E)-2-(1-hydroxyalkyl)alk-2-enenitriles with 100percent retention of the configur

Full text of DOI:10.1039/c39830000170

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