Chemistry Letters p. 725 - 728 (1983)
Update date:2022-08-04
Topics:
Sato, Kikumasa
Miyamoto, Osamu
Inoue, Seiichi
Furusawa, Fumio
Matsuhashi, Yasusuke
As the key compound for the construction of cisoid terpenoids, (2Z,6Z)-8-benzyloxy-1-chloro-2,6-dimethylocta-2,6-diene was sinthesized stereoselectively via the Wittig reaction starting from nerol.The ten-carbon building block was coupled with prenyl or neryl p-tolyl sulfone to afford, after reductive desulfonylation, (Z,Z)-farnesol and (Z,Z,Z)-nerylnerol, respectively.
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