PENTAHALOPHENYLARGENTATE(I) COMPLEXES

Article abstract of DOI:10.1016/S0022-328X(00)98739-4

The reaction of (CF3COO)Ag with LiR gives (R = C6F5 or C6Cl5).The latter react with acids HX to give organoargentate(I) derivatives of the types (X = CH3COO, CF3COO or 8-oxyquinolate) or 2<2BiBzIm> (BiBzIm = bibenzimidazolate), whilst the reaction with silver salts AgX yields <2X> (X = NO3 or CF3COO) or AgR (X = ClO4).