Bulletin of the Chemical Society of Japan p. 1095 - 1100 (1983)
Update date:2022-08-02
Topics:
Kawana, Masajiro
Koresawa, Tetsuo
Kuzuhara, Hiroyoshi
The reactions of methyl 5-O-benzyl-2-O- and -3-O-tosyl-β-D-ribofuranosides with methylmagnesium iodide gave, in one-step, 2-deoxy-3-C- and 3-deoxy-2-C-methyl branched-chain sugars, respectively. These sugars were anomerized with Grignard reagents; the thermodynamically more stable anomers were converted preferentially into the respective less stable anomers.
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(1966)
