Efficient synthesis of 2-deoxyglycosyl-1-O-acyl esters via 2-deoxyglycosyl phosphorodithioates as glycosyl donors

Article abstract of DOI:10.1055/s-1994-25554

An efficient glycosylation of carboxylic acids 2a-p has been developed employing 2-deoxyglycosyl phosphorodithioates 1a-h as glycosyl donors and Ag + salts as activators. In the case of aliphatic acids the method is highly β-stereoselective. Stereoselecti